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WHAT IS PLASMA?

Plasma is often called the "Fourth State of Matter," the other three being solid, liquid and gas. A plasma is a distinct state of matter containing a significant number of electrically charged particles, a number sufficient to affect its electrical properties and behavior. In addition to being important in many aspects of our daily lives, plasmas are estimated to constitute more than 99 percent of the visible universe.

In an ordinary gas each atom contains an equal number of positive and negative charges; the positive charges in the nucleus are surrounded by an equal number of negatively charged electrons, and each atom is electrically "neutral." A gas becomes a plasma when the addition of heat or other energy causes a significant number of atoms to release some or all of their electrons. The remaining parts of those atoms are left with a positive charge, and the detached negative electrons are free to move about. Those atoms and the resulting electrically charged gas are said to be "ionized." When enough atoms are ionized to significantly affect the electrical characteristics of the gas, it is a plasma.

In many cases interactions between the charged particles and the neutral particles are important in determining the behavior and usefulness of the plasma. The type of atoms in a plasma, the ratio of ionized to neutral particles and the particle energies all result in a broad spectrum of plasma types, characteristics and behaviors. These unique behaviors cause plasmas to be useful in a large and growing number of applications important to our lives and to the world around us.

Origin of the Term "Plasma" for Ionized Gases

Many wonder how the term "plasma" became applied to an ionized gas. Irving Langmuir, a researcher working to understand electric discharges, was the first to use the term in this way. The following explanatory excerpt is from: G. L. Rogoff, Guest Editorial, Special Issue on Applications of Partially Ionized Plasmas, G. L. Rogoff, Ed., IEEE Transactions on Plasma Science, vol. 19, p. 989, Dec. 1991. (See helpful definitions below.)  

During the 1920's Irving Langmuir was studying various types of mercury-vapor discharges, and he noticed similarities in their structure - near the boundaries as well as in the main body of the discharge. While the region immediately adjacent to a wall or electrode was already called a "sheath," there was no name for the quasi-neutral stuff filling most of the discharge space. He decided to call it "plasma."

While his relating the term to blood plasma has been acknowledged by colleagues who worked with him at the General Electric Research Laboratory, [1], [2], the basis for that connection is unclear. One version [2] of the story has it that the similarity was in carrying particles, while another account [3] speculated that it was in the Greek origin of the term, meaning "to mold," since the glowing discharge usually molded itself to the shape of its container. In any case, it appears that the first published use of the term was in Langmuir's "Oscillations in Ionized Gases," published in 1928 in the Proceedings of the National Academy of Sciences [4].

Thus the term "plasma" was first used to describe partially (if not weakly) ionized gases. The term plasma apparently did not find immediate widespread use in the scientific community. It did eventually catch on, however, but in some cases the term was inappropriately limited to highly ionized gases.

REFERENCES

  • [1] L. Tonks, "The birth of 'plasma'" Amer. J. Phys., vol. 35, pp. 857-858, 1967.
  • [2] Letter from H. M. Mott-Smith to A. M. Bueche, Apr. 20, 1967 (on file at Communications Operation, General Electric R&D Center, Schenectady, NY).
  • [3] S. C. Brown, "A short history of gaseous electronics," in Gaseous Electronics, vol. 1, M. N. Hirsh and H. J. Oskam, Eds. New York: Academic, 1978, pp. 1-18.
  • [4] I. Langmuir, "Oscillations in ionized gases," Proc. Nat. Acad. Sci. U.S., vol. 14, p. 628, 1928; also available in The Collected Works of Irving Langmuir, vol. 5, C. G. Suits, Ed. New York: Pergamon, 1961, pp. 111-120.

Definitions:

Discharge: An electric discharge is the glowing gas that carries electricity between two electrodes when voltage is applied between them.

Quasi-neutral: "Quasi-neutral" refers to there being about equal numbers of positive ions and negative electrons in the gas; if there were exactly equal numbers of opposite charges, the gas would be exactly electrically neutral. (A plasma need not be exactly electrically neutral.)

Partially ionized: The terms "partially ionized," "weakly ionized" and "highly ionized" indicate qualitatively what fraction of the gas atoms are charged.

PLASMA APPLICATIONS

Plasmas underlie numerous important technological applications and devices as well as our understanding of much of the universe around us.They provide the foundation and underpinnings for present applications such as plasma processing of semiconductors, sterilization of some medical products, lamps, lasers, diamond coated films, high power microwave sources, and pulsed power switches.

They also provide the foundation for important potential applications such as the generation of electrical energy from fusion and pollution control and removal of hazardous chemicals.

Plasma science encompasses a variety of science disciplines ranging from plasma physics to aspects of chemistry, atomic and molecular physics, and material science. Its broad, interdisciplinary nature also characterizes its plasma physics component, which includes ionized gases that range from weakly ionized to highly ionized, from collisional to collisionless, and from cold to hot. These terms characterize various plasmas ranging from relatively high-pressure gases with a small fraction of the atoms ionized and relatively low charged-particle temperatures -- for example, plasmas used in computer-chip processing and light sources -- to those in very low density gases with a large fraction of the gas atoms ionized and very high-temperature charged particles -- for example, fusion plasmas.

Different types of plasmas underlie different applications and different natural phenomena. However, many fundamental considerations span the broad parameter ranges that characterize the many natural and man-made plasmas that are important in our lives.

The diversity of what is included in "plasma science" makes the subject difficult to characterize. However, it is that same diversity that makes it such an important contributor to a wide range of applications and technological developments. Below is a list of just some of the many technological applications of plasmas:

INDUSTRIAL / COMMERCIAL APPLICATIONS OF PLASMAS

Processing

♢ Surface Processing
♢ Nonequilibrium (low pressure)
♢ Thermal (high pressure)

Volume Processing

♢ Flue gas treatment
♢ Metal recovery
♢ Waste treatment

Chemical Synthesis

♢ Plasma spraying
♢ Diamond film deposition
♢ Ceramic powders

Light Sources

♢ High intensity discharge lamps
♢ Low pressure lamps
♢ Specialty sources

Surface Treatment

♢ Ion implantation
♢ Hardening
♢ Welding
♢ Cutting
♢ Drilling

Propulsion

   

Flat-Panel Displays

♢ Field-emitter arrays
♢ Plasma displays

Radiation Processing

♢ Water purification
♢ Plant growth

Switches

♢ Electric power
♢ Pulsed power

Energy Converters

♢ MHD converters
♢ Thermionic energy converters

Medicine

♢ Surface treatment
♢ Instrument sterilization

Isotope Separation

   

Beam Sources

   

Lasers

   

Material Analysis

   

One company's product may be another company's process. The specific applications of some classes of plasmas are too numerous to list, e.g., Lasers, Lamps...

Some applications are listed as the plasma device itself; others are listed as one level beyond that, i.e., as the applications of the plasma device.